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The Chemical History of a Candle

Page 31 of 90, printed 31

substance which acted upon the water in the way that Sir Humphrey Davy shewed us[13], and which I am now going to recall to your minds by making again an experiment upon that dish. It is a thing which we have to handle very carefully, for you see, if I allow a little splash of water to come upon this mass, it sets fire to part of it; and if there were free access of air, it would quickly set fire to the whole. Now, this is a metal a beautiful and bright metal which rapidly changes in the air, and, as you know, rapidly changes in water. I will put a piece on the water, and you see it burns beautifully, making a floating lamp, using the water in the place of air. Again, if we take a few iron filings or turnings, and put them in water, we find that they likewise undergo an alteration. They do not change so much as this potassium does, but they change somewhat in the same way; they become rusty, and shew an action upon the water, though in a different degree of intensity to what this beautiful metal does: but they act upon the water in the same manner generally as this potassium. I want you to put these different facts together in your minds. I have another metal here [zinc], and when we examined it with regard to the solid substance produced by its combustion, we had an opportunity of seeing that it burned; and I suppose, if I take a little strip of this zinc and put it over the candle, you will see something half-way, as it were, between the combustion of potassium on the water and the action of iron, you see there is a sort of combustion. It has burned, leaving a white ash or residuum, and here also we find that the metal has a certain amount of action upon water. By degrees we have learned how to modify the action of these different substances, and to make them tell us what we want to know. And now, first of all, I take iron. It is a common thing in all chemical reactions, where we get any result of this kind, to find that it is increased by the action of heat; and if we want to examine minutely and carefully the action of bodies one upon another, we often have to refer to the action of heat. You are aware, I believe, that iron-filings burn beautifully in the air; but I am about to shew you an experiment of this kind, because it will impress upon you what I am going to say about iron in its action on water. If I take a flame and make it hollow; you know why, because I want to get air to it and into it, and therefore I make it hollow and then take a few iron-filings and drop them into the flame, you see how well they burn. That combustion results from the chemical action which is going on when we ignite those particles. And so we proceed to consider these different effects, and ascertain what iron will do when it meets with water. It will 31
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