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The Chemical History of a Candle

Page 23 of 90, printed 23

you to see what will be the result of the combustion of this zinc. Here it is burning burning beautifully like a candle, I may say. But what is all that smoke, and what are those little clouds of wool which will come to you if you cannot come to them, and make themselves sensible to you in the form of the old philosophic wool, as it was called? We shall have left in that crucible, also, a quantity of this woolly matter. But I will take a piece of this same zinc and make an experiment a little more closely at home, as it were. You will have here the same thing happening. Here is the piece of zinc, there [pointing to a jet of hydrogen] is the furnace, and we will set to work and try and burn the metal. It glows, you see: there is the combustion, and there is the white substance into which it burns. And so, if I take that flame of hydrogen as the representative of a candle, and shew you a substance like zinc burning in the flame, you will see that it was merely during the action of combustion that this substance glowed while it was kept hot; and if I take a flame of hydrogen, and put this white substance from the zinc into it, look how beautifully it glows, and just because it is a solid substance. I will now take such a flame as I had a moment since, and set free from it the particles of carbon. Here is some camphine, which will burn with a smoke; but if I send these particles of smoke through this pipe into the hydrogen flame, you will see they will burn and become luminous, because we heat them a second time. There they are. Those are the particles of carbon re-ignited a second time. They are those particles which you can easily see by holding a piece of paper behind them, and which, whilst they are in the flame, are ignited by the heat produced, and, when so ignited, produce this brightness. When the particles are not separated, you get no brightness. The flame of coal-gas owes its brightness to the separation, during combustion, of these particles of carbon, which are equally in that as in a candle. I can very quickly alter that arrangement. Here, for instance, is a bright flame of gas. Supposing I add so much air to the flame as to cause it all to burn before those particles are set free, I shall not have this brightness; and I can do that in this way: If I place over the jet this wire-gauze cap, as you see, and then light the gas over it, it burns with a non-luminous flame, owing to its having plenty of air mixed with it before it burns; and if I raise the gauze, you see it does not burn below[10]. There is plenty of carbon in the gas; but, because the atmosphere can get to it, and mix with it before it burns, you see how pale and blue the flame is. And if I blow upon a bright gas-flame, so as to consume all this carbon before it gets heated to the glowing point, it 23
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