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Elements of Chemistry

Page 89 of 329, printed 89

uniting with each other, and forming what are called _alloys_[22], in common language. Most of these, like all combinations, are susceptible of several degrees of saturation; the greater number of these alloys are more brittle than the pure metals of which they are composed, especially when the metals alloyed together are considerably different in their degrees of fusibility. To this difference in fusibility, part of the phenomena attendant upon _alloyage_ are owing, particularly the property of iron, called by workmen _hotshort_. This kind of iron must be considered as an alloy, or mixture of pure iron, which is almost infusible, with a small portion of some other metal which fuses in a much lower degree of heat. So long as this alloy remains cold, and both metals are in the solid state, the mixture is malleable; but, if heated to a sufficient degree to liquify the more fusible metal, the particles of the liquid metal, which are interposed between the particles of the metal remaining solid, must destroy their continuity, and occasion the alloy to become brittle. The alloys of mercury, with the other metals, have usually been called _amalgams_, and we see no inconvenience from continuing the use of that term. Sulphur, phosphorus, and charcoal, readily unite with metals. Combinations of sulphur with metals are usually named _pyrites_. Their combinations with phosphorus and charcoal are either not yet named, or have received new names only of late; so that we have not scrupled to change them according to our principles. The combinations of metal and sulphur we call _sulphurets_, those with phosphorus _phosphurets_, and those formed with charcoal _carburets_. These denominations are extended to all the combinations into which the above three substances enter, without being previously oxygenated. Thus, the combination of sulphur with potash, or fixed vegetable alkali, is called _sulphuret of potash_; that which it forms with ammoniac, or volatile alkali, is termed _sulphuret of ammoniac_. Hydrogen is likewise capable of combining with many combustible substances. In the state of gas, it dissolves charcoal, sulphur, phosphorus, and several metals; we distinguish these combinations by the terms, _carbonated hydrogen gas_, _sulphurated hydrogen gas_, and _phosphorated hydrogen gas_. The sulphurated hydrogen gas was called _hepatic air_ by former chemists, or _foetid air from sulphur_, by Mr Scheele. The virtues of several mineral waters, and the foetid smell of animal excrements, chiefly arise from the presence of this gas. The 89
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