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Elements of Chemistry

Page 85 of 329, printed 85

Caloric necessary for supporting one pound of carbonic acid in the state of gas, 20.97960. [Note A: All these relative quantities of caloric are expressed by the number of pounds of ice, and decimal parts, melted during the several operations.--E.] _Combustion of Hydrogen Gas._ In the combustion of one pound of hydrogen gas, 5 libs. 10 oz. 5 gros 24 grs. of oxygen gas are absorbed, and 6 libs. 10 oz. 5 gros 24 grs. of water are formed. Caloric from each lib. of hydrogen gas, 295.58950. Caloric from each lib. of oxygen gas, 52.16280. Caloric disengaged during the formation of each pound of water, 44.33840. Caloric retained by each lib. of oxygen after combustion with hydrogen, 14.50386. Caloric retained by each lib. of water at the temperature of Zero (32 ), 12.32823. _Of the Formation of Nitric Acid._ When we combine nitrous gas with oxygen gas, so as to form nitric or nitrous acid a degree of heat is produced, which is much less considerable than what is evolved during the other combinations of oxygen; whence it follows that oxygen, when it becomes fixed in nitric acid, retains a great part of the heat which it possessed in the state of gas. It is certainly possible to determine the quantity of caloric which is disengaged during the combination of these two gasses, and consequently to determine what quantity remains after the combination takes place. The first of these quantities might be ascertained, by making the combination of the two gasses in an apparatus surrounded by ice; but, as the quantity of caloric disengaged is very inconsiderable, it would be necessary to operate upon a large quantity of the two gasses in a very troublesome and complicated apparatus. By this consideration, Mr de la Place and I have hitherto been prevented from making the 85
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