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Elements of Chemistry

Page 35 of 329, printed 35

atmosphere, and that the passing of the ether from the liquid to the aeriform state is accompanied by a considerable lessening of heat; because, during the evaporation, a part of the caloric, which was before in a free state, or at least in equilibrio in the surrounding bodies, combines with the ether, and causes it to assume the aeriform state. The same experiment succeeds with all evaporable fluids, such as alkohol, water, and even mercury; with this difference, that the atmosphere formed in the receiver by alkohol only supports the attached barometer about one inch in winter, and about four or five inches in summer; that formed by water, in the same situation, raises the mercury only a few lines, and that by quicksilver but a few fractions of a line. There is therefore less fluid evaporated from alkohol than from ether, less from water than from alkohol, and still less from mercury than from either; consequently there is less caloric employed, and less cold produced, which quadrates exactly with the results of these experiments. Another species of experiment proves very evidently that the aeriform state is a modification of bodies dependent on the degree of temperature, and on the pressure which these bodies undergo. In a Memoir read by Mr de la Place and me to the Academy in 1777, which has not been printed, we have shown, that, when ether is subjected to a pressure equal to twenty-eight inches of the barometer, or about the medium pressure of the atmosphere, it boils at the temperature of about 32 (104 ), or 33 (106.25 ), of the thermometer. Mr de Luc, who has made similar experiments with spirit of wine, finds it boils at 67 (182.75 ). And all the world knows that water boils at 80 (212 ). Now, boiling being only the evaporation of a liquid, or the moment of its passing from the fluid to the aeriform state, it is evident that, if we keep ether continually at the temperature of 33 (106.25 ), and under the common pressure of the atmosphere, we shall have it always in an elastic aeriform state; and that the same thing will happen with alkohol when above 67 (182.75 ), and with water when above 80 (212 ); all which are perfectly conformable to the following experiment[7]. I filled a large vessel ABCD (Plate VII. Fig. 16.) with water, at 35 (110.75 ), or 36 (113 ); I suppose the vessel transparent, that we may see what takes place in the experiment; and we can easily hold the hands in water at that temperature without inconvenience. Into it I plunged some narrow necked bottles F, G, which were filled with the water, after 35
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