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Elements of Chemistry

Page 299 of 329, printed 299

trials. This furnace, which, according to the above stated rules, is in form of an eliptical spheroid, is represented Pl. XIII. Fig. 6. ABCD; it is cut off at the two ends by two plains, which pass, perpendicular to the axis, through the foci of the elipse. From this shape it is capable of containing a considerable quantity of charcoal, while it leaves sufficient space in the intervals for the passage of the air. That no obstacle may oppose the free access of external air, it is perfectly open below, after the model of Mr Macquer's melting furnace, and stands upon an iron tripod. The grate is made of flat bars set on edge, and with considerable interstices. To the upper part is added a chimney, or tube, of baked earth, ABFG, about eighteen feet long, and almost half the diameter of the furnace. Though this furnace produces a greater heat than any hitherto employed by chemists, it is still susceptible of being considerably increased in power by the means already mentioned, the principal of which is to render the tube as bad a conductor of heat as possible, by making it double, and filling the interval with rammed charcoal. When it is required to know if lead contains any mixture of gold or silver, it is heated in a strong fire in capsules of calcined bones, which are called cuppels. The lead is oxydated, becomes vitrified, and sinks into the substance of the cuppel, while the gold or silver, being incapable of oxydation, remain pure. As lead will not oxydate without free access of air, this operation cannot be performed in a crucible placed in the middle of the burning coals of a furnace, because the internal air, being mostly already reduced by the combustion into azotic and carbonic acid gas, is no longer fit for the oxydation of metals. It was therefore necessary to contrive a particular apparatus, in which the metal should be at the same time exposed to the influence of violent heat, and defended from contact with air rendered incombustible by its passage through burning coals. The furnace intended for answering this double purpose is called the cuppelling or essay furnace. It is usually made of a square form, as represented Pl. XIII. Fig. 8. and 10. having an ash-hole AABB, a fire-place BBCC, a laboratory CCDD, and a dome DDEE. The muffle or small oven of baked earth GH, Fig. 9. being placed in the laboratory of the furnace upon cross bars of iron, is adjusted to the opening GG, and luted with clay softened in water. The cuppels are placed in this oven or muffle, and charcoal is conveyed into the furnace 299
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