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Elements of Chemistry

Page 277 of 329, printed 277

emptying during the process, that there may be no interruption to the combustion; 4, 5, is a tube of glass filled with deliquescent salts, for drying the air as much as possible in its passage; and the weight of this tube and its contained salts, at the beginning of the experiment, being known, it is easy to determine the quantity of water absorbed by them from the air. From this deliquescent tube the air is conducted through the pipe 5, 6, 7, 8, 9, 10, to the lamp 11, where it spreads on both sides of the wick, as before described, and feeds the flame. One part of this air, which serves to keep up the combustion of the oil, forms carbonic acid gas and water, by oxygenating its elements. Part of this water condenses upon the sides of the pitcher A, and another part is held in solution in the air by means of caloric furnished by the combustion. This air is forced by the compression of the gazometer to pass through the tube 12, 13, 14, 15, into the bottle 16, and the worm 17, 18, where the water is fully condensed from the refrigeration of the air; and, if any water still remains in solution, it is absorbed by deliquescent salts contained in the tube 19, 20. All these precautions are solely intended for collecting and determining the quantity of water formed during the experiment; the carbonic acid and azotic gas remains to be ascertained. The former is absorbed by caustic alkaline solution in the bottles 22 and 25. I have only represented two of these in the figure, but nine at least are requisite; and the last of the series may be half filled with lime-water, which is the most certain reagent for indicating the presence of carbonic acid; if the lime-water is not rendered turbid, we may be certain that no sensible quantity of that acid remains in the air. The rest of the air which has served for combustion, and which chiefly consists of azotic gas, though still mixed with a considerable portion of oxygen gas, which has escaped unchanged from the combustion, is carried through a third tube 28, 29, of deliquescent salts, to deprive it of any moisture it may have acquired in the bottles of alkaline solution and lime-water, and from thence by the tube 29, 30, into a gazometer, where its quantity is ascertained. Small essays are then taken from it, which are exposed to a solution of sulphuret of potash, to ascertain the proportions of oxygen and azotic gas it contains. In the combustion of oils the wick becomes charred at last, and obstructs the rise of the oil; besides, if we raise the wick above a 277
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