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Elements of Chemistry

Page 228 of 329, printed 228

from that of atmospheric air. Hence I may take for granted, till farther experiments give us better information upon this subject, that atmospherical air is dilated 1/210 part, and hydrogen gas 1/190 part for each degree of the thermometer; but, as there is still great uncertainty upon this point, we ought always to operate in a temperature as near as possible to the standard of 10 , (54.5 ) by this means any errors in correcting the weight or volume of gasses by reducing them to the common standard, will become of little moment. The calculation for this correction is extremely easy. Divide the observed volume of air by 210, and multiply the quotient by the degrees of temperature above or below 10 (54.5 ). This correction is negative when the actual temperature is above the standard, and positive when below. By the use of logarithmical tables this calculation is much facilitated[59]. SECT. VII. _Example for calculating the Corrections relative to the Variations of Pressure and Temperature._ CASE. In the jar A, Pl. IV. Fig. 3. standing in a water apparatus, is contained 353 cubical inches of air; the surface of the water within the jar at EF is 4-1/2 inches above the water in the cistern, the barometer is at 27 inches 9-1/2 lines, and the thermometer at 15 (65.75 ). Having burnt a quantity of phosphorus in the air, by which concrete phosphoric acid is produced, the air after the combustion occupies 295 cubical inches, the water within the jar stands 7 inches above that in the cistern, the barometer is at 27 inches 9-1/4 lines, and the thermometer at 16 (68 ). It is required from these data to determine the actual volume of air before and after combustion, and the quantity absorbed during the process. _Calculation before Combustion._ 228
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