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Elements of Chemistry

Page 226 of 329, printed 226

28 inches barometrical pressure; that is to say, the same gas or air which at 28.5 inches of the barometer occupies 100 cubical inches of volume, will occupy 101.786 cubical inches when the barometer is at 28 inches. It is equally easy to calculate the weight of this gas, occupying 100 cubical inches, under 28.5 inches of barometrical pressure; for, as it corresponds to 101.786 cubical inches at the pressure of 28, and as, at this pressure, and at 10 (54.5 ) of temperature, each cubical inch of oxygen gas weighs half a grain, it follows, that 100 cubical inches, under 28.5 barometrical pressure, must weigh 50.893 grains. This conclusion might have been formed more directly, as, since the volume of elastic fluids is in the inverse ratio of their compression, their weights must be in the direct ratio of the same compression: Hence, since 100 cubical inches weigh 50 grains, under the pressure of 28 inches, we have the following statement to determine the weight of 100 cubical inches of the same gas as 28.5 barometrical pressure, 28 : 50 :: 28.5 : x, the unknown quantity, = 50.893. The following case is more complicated: Suppose the jar A, Pl. XII. Fig. 18. to contain a quantity of gas in its upper part ACD, the rest of the jar below CD being full of mercury, and the whole standing in the mercurial bason or reservoir GHIK, filled with mercury up to EF, and that the difference between the surface CD of the mercury in the jar, and EF, that in the cistern, is six inches, while the barometer stands at 27.5 inches. It is evident from these data, that the air contained in ACD is pressed upon by the weight of the atmosphere, diminished by the weight of the column of mercury CE, or by 27.5 - 6 = 21.5 inches of barometrical pressure. This air is therefore less compressed than the atmosphere at the mean height of the barometer, and consequently occupies more space than it would occupy at the mean pressure, the difference being exactly proportional to the difference between the compressing weights. If, then, upon measuring the space ACD, it is found to be 120 cubical inches, it must be reduced to the volume which it would occupy under the mean pressure of 28 inches. This is done by the following statement: 120 : x, the unknown volume, :: 21.5 : 28 inversely; this gives x = 120 21.5 / 28 = 92.143 cubical inches. In these calculations we may either reduce the height of the mercury in the barometer, and the difference of level in the jar and bason, into lines or decimal fractions of the inch; but I prefer the latter, as it is more readily calculated. As, in these operations, which frequently 226
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