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Elements of Chemistry

Page 219 of 329, printed 219

bodies with the requisite precision as to quantity and proportion; it is certainly proper to endeavour to simplify these, and to render them less costly; but this ought by no means to be attempted at the expence of their conveniency of application, and much less of their accuracy. SECT. III. _Some other methods of measuring the volume of Gasses._ The gazometer described in the foregoing section is too costly and too complicated for being generally used in laboratories for measuring the gasses, and is not even applicable to every circumstance of this kind. In numerous series of experiments, more simple and more readily applicable methods must be employed. For this purpose I shall describe the means I used before I was in possession of a gazometer, and which I still use in preference to it in the ordinary course of my experiments. Suppose that, after an experiment, there is a residuum of gas, neither absorbable by alkali nor water, contained in the upper part of the jar AEF, Pl. IV. Fig. 3. standing on the shelf of a pneumato-chemical apparatus, of which we wish to ascertain the quantity, we must first mark the height to which the mercury or water rises in the jar with great exactness, by means of slips of paper pasted in several parts round the jar. If we have been operating in mercury, we begin by displacing the mercury from the jar, by introducing water in its stead. This is readily done by filling a bottle quite full of water; having stopped it with your finger, turn it up, and introduce its mouth below the edge of the jar; then, turning down its body again, the mercury, by its gravity, falls into the bottle, and the water rises in the jar, and takes the place occupied by the mercury. When this is accomplished, pour so much water into the cistern ABCD as will stand about an inch over the surface of the mercury; then pass the dish BC, Pl. V. Fig. 9. under the jar, and carry it to the water cistern, Fig. 1. and 2. We here exchange the gas into another jar, which has been previously graduated in the manner to be afterwards described; and we thus judge of the quantity or volume of the gas by means of the degrees which it occupies in the graduated jar. There is another method of determining the volume of gas, which may 219
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